92747
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92747
Fluka
2-(Trimethylsilyl)ethanol
purum, ≥98.0% (GC)
| Synonym: | (2-Hydroxyethyl)trimethylsilane |
| CAS Number: | 2916-68-9 |
| Linear Formula: | (CH3)3SiCH2CH2OH |
| Molecular Weight: | 118.25 |
| Beilstein Registry Number: | 1732034 |
| EC Number: | 220-844-5 |
| MDL number: | MFCD00002825 |
| PubChem Substance ID: | 24889708 |
Description
| Other Notes | Component for protecting groups cleavable with fluoride ion1,2,3; Anomeric protection of carbohydrates4,5 |
Properties
| grade | purum |
| assay | ≥98.0% (GC) |
| refractive index | n |
| n | |
| bp | 71-73 °C/35 mmHg(lit.) |
| density | 0.825 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Risk Statements | 10 |
| Safety Statements | 16 |
| RIDADR | UN1987 3/PG 3 |
| WGK Germany | 3 |
| RTECS | KM5480000 |
| Flash Point(F) | 132.8 °F |
| Flash Point(C) | 56 °C |
References
| Cited Reference | 1. P. Sieber Helv. Chim. Acta 60, 2711, (1977) |
| 2. L.A. Carpino, J.H. Tsav J. Chem. Soc., Chem. Commun., 358, (1978) | |
| 3. K.L. Rinehart et al. J. Am. Chem. Soc. 109, 6846, (1987) | |
| 4. R. Saksena et al. J. Carbohydr. Chem. 21, 453, (2002) | |
| 5. K. Jansson et al. J. Org. Chem. 53, 5629, (1988) | |
| Beilstein | Beil. 4,IV,3951 |
| Fieser | Fieser 8,510 |
| reference | Aldrich MSDS 1, 1798:B / Corp MSDS 1 (2), 3497:B / FT-IR 1 (2), 1108:D / FT-IR 2 (3), 4365:A / FT-NMR 1 (3), 654:A / RegBook 1 (2), 2965:H / Sigma FT-IR 1 (2), 984:A / Structure Index 1, 469:D:4 / Vapor Phase 3, 1638:B |
